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Aging Resistance Evaluation of Aged Paper Reinforced with Different Nanocelluloses
Received:June 06, 2023    Click here to download the full text
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Author NameAffiliation
Cao Xian State Key Lab of Pulp and Paper Engineering, School of Light Industry and Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640, China
Lingnan Literature Preservation Research Center, South China University of Technology, Guangzhou, Guangdong Province, 510640, China 
He Bei State Key Lab of Pulp and Paper Engineering, School of Light Industry and Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640, China
Lingnan Literature Preservation Research Center, South China University of Technology, Guangzhou, Guangdong Province, 510640, China 
Wang Jianlin State Key Lab of Pulp and Paper Engineering, School of Light Industry and Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640, China
Lingnan Literature Preservation Research Center, South China University of Technology, Guangzhou, Guangdong Province, 510640, China 
Zhang Chunhui State Key Lab of Pulp and Paper Engineering, School of Light Industry and Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640, China
Lingnan Literature Preservation Research Center, South China University of Technology, Guangzhou, Guangdong Province, 510640, China 
Tang Donglin School of Materials Science and Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640, China 
Liang Qingyou Analytical and Testing Center, South China University of Technology, Guangzhou, Guangdong Province, 510640, China 
Liu Chuanfu State Key Lab of Pulp and Paper Engineering, School of Light Industry and Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640, China
Lingnan Literature Preservation Research Center, South China University of Technology, Guangzhou, Guangdong Province, 510640, China 
Fan Huiming State Key Lab of Pulp and Paper Engineering, School of Light Industry and Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640, China
Lingnan Literature Preservation Research Center, South China University of Technology, Guangzhou, Guangdong Province, 510640, China 
Ren Junli State Key Lab of Pulp and Paper Engineering, School of Light Industry and Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640, China
Lingnan Literature Preservation Research Center, South China University of Technology, Guangzhou, Guangdong Province, 510640, China 
 
Abstract:Paper documents experience severe acidification and embrittlement. Nanocellulose is an excellent reinforcement material for paper documents owing to its compatibility and excellent mechanical strength. However, little research has been conducted on the aging resistance of nanocellulose-reinforced paper. In this study, six types of nanocelluloses were used to reinforce aged paper. The reinforcement and anti-aging performances were evaluated, and the anti-aging mechanism was further clarified. Nanocellulose with a high degree of polymerization can better enhance aged paper, and non-chemical nanocellulose also shows better anti-aging performance, such as nanocellulose prepared by mechanical or biological methods. However, nanocellulose prepared using chemical methods exhibits poor reinforcement and anti-aging performance. This is because it has a small particle size that is not beneficial for physical crosslinking with paper fibers. More importantly, the introduction of acidic or oxidizing groups on nanocellulose accelerates the acid hydrolysis and oxidation rate of paper fibers, especially nanocellulose prepared by 2,2,6,6-tetramethylpiperidine-1-oxyl oxidation, which should not be used to protect paper documents.
keywords:protection of paper documents  nanocellulose  reinforcement  aging resistance
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